Electrolysis | Definition, Uses, & Facts (2024)

chemical reaction

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electrolysis, process by which electric current is passed through a substance to effect a chemical change. The chemical change is one in which the substance loses or gains an electron (oxidation or reduction). The process is carried out in an electrolytic cell, an apparatus consisting of positive and negative electrodes held apart and dipped into a solution containing positively and negatively charged ions. The substance to be transformed may form the electrode, may constitute the solution, or may be dissolved in the solution. Electric current (i.e., electrons) enters through the negatively charged electrode (cathode); components of the solution travel to this electrode, combine with the electrons, and are transformed (reduced). The products can be neutral elements or new molecules. Components of the solution also travel to the other electrode (anode), give up their electrons, and are transformed (oxidized) to neutral elements or new molecules. If the substance to be transformed is the electrode, the reaction is often one in which the electrode dissolves by giving up electrons.

Electrolysis is used extensively in metallurgical processes, such as in extraction (electrowinning) or purification (electrorefining) of metals from ores or compounds and in deposition of metals from solution (electroplating). Metallic sodium and chlorine gas are produced by the electrolysis of molten sodium chloride; electrolysis of an aqueous solution of sodium chloride yields sodium hydroxide and chlorine gas. Hydrogen and oxygen are produced by the electrolysis of water.

Electrolysis | Definition, Uses, & Facts (1)

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Electricity: Short Circuits & Direct Currents

The Editors of Encyclopaedia Britannica This article was most recently revised and updated by Adam Augustyn.

Electrolysis | Definition, Uses, & Facts (2024)

FAQs

What is electrolysis and its uses? ›

electrolysis, process by which electric current is passed through a substance to effect a chemical change. The chemical change is one in which the substance loses or gains an electron (oxidation or reduction).

What are the important facts about electrolysis? ›

Electrolysis is the passing of a direct electric current through an electrolyte which is producing chemical reactions at the electrodes and decomposition of the materials. The main components required to achieve electrolysis are an electrolyte, electrodes, and an external power source.

How is electrolysis used in everyday life? ›

Electrolysis is one of those processes which are widely used in the metal industry. Whether it's the extraction of metals from their ores, purification of metals, or electroplating of metals; all these applications involve electrolysis. Moreover, it is extensively used for manufacturing industrial chemicals like brine.

How does electrolysis work simple? ›

Electrolysis works by passing an electric current through an electrolyte solution. The electric current causes the ions in the solution to move towards the electrodes, where they undergo chemical reactions that result in the release of either positively or negatively charged particles.

Where to use electrolysis? ›

Electrolysis can treat most areas of the body, including the: Back. Bikini line, thighs and lower legs. Breasts and abdomen.

What are the reasons for using electrolysis? ›

The purpose of using electrolysis in metal extraction is to separate metal ions from a solution or molten substance and deposit them as pure metal at the electrodes. Electrolysis is particularly useful for extracting metals that cannot be obtained through reduction or smelting, such as aluminum and magnesium.

What are some interesting facts about water electrolysis? ›

Real World Science: Water electrolysis can be used as a form of renewable energy to provide many benefits. Hydrogen produced in this reaction can be stored in fuel cells and serve as electricity, decreasing CO2 emissions and excess energy generated by solar power or wind turbines.

What does electrolysis damage? ›

Just one poor ground connection on equipment using a conductive water-based fluid can cause electrolysis to quickly corrode components, beginning with the least noble metal in the system. Aluminum, cast iron, and steel will typically be the first metals to be attacked.

What is a downside to electrolysis? ›

Electrolysis Cons

It's a time-consuming procedure requiring multiple sessions. Skin discoloration is a possibility. The electricity in the device can actually destroy the capillaries in the surrounding areas. It can be very painful. It is not recommended for people with rosacea since the skin is so easily irritated.

What else can electrolysis be used for? ›

Electrolysis can be used to purify metals or extract them from a solution or break down substances into their individual components. For example, a sodium chloride solution can be turned into chlorine gas and sodium hydroxide, while the electrolysis of water produces hydrogen gas and oxygen.

Why is electrolysis needed? ›

Electrolysis gives us a means to reduce metals that we would otherwise be incapable of producing. For example, electrolysis of aluminium means we can have aluminium products. Such lightweight materials are important for a whole variety of reasons, from drinking cans to aircraft.

Does electrolysis use a lot of electricity? ›

As of 2022, commercial electrolysis requires around 53 kWh of electricity to produce one kg of hydrogen, which holds 39.4 kWh (HHV) of energy.

How painful is electrolysis? ›

You'll feel a sharp sting or temporary warmth as each hair follicle is treated. How much the process hurts depends on how you react to pain and the area being treated.

What are three uses of electrolysis? ›

Applications of electrolysis:
  • Electroplating with metals.
  • Electrorefining of metals.
  • Extraction of metals.
  • Purification of metals.
  • Electrolytic reduction of metals from their compounds.
  • Metal cleaning: dirty metals can be cleaned.
Jul 3, 2022

What is the point of electrolysis? ›

Electrolysis can be used to separate a substance into its original components/elements and it was through this process that a number of elements have been discovered and are still produced in today's industry.

What is the common example of electrolysis? ›

A familiar example of electrolysis is recharging a battery, which involves use of an external power source to drive the spontaneous (discharge) cell reaction in the reverse direction, restoring to some extent the composition of the half-cells and the voltage of the battery.

What are the products of electrolysis useful for? ›

Electrolysis is often used to extract metals from molten ores or molten ionic compounds. Aluminium, for example, can be extracted from its ore (known as bauxite) using this process. The bauxite is firstly converted into aluminium oxide and then electrolysed in a solution of molten cryolite (another aluminium compound).

What metal is electrolysis used for? ›

Electrolysis is used to extract metals that are more reactive than carbon, such as aluminum. These more reactive metals can't be extracted by heating them with carbon. Metals that are less reactive than carbon, such as iron, can be extracted by heating with carbon, or with electrolysis.

What is electrolysis used for in medicine? ›

With improvements in surgical technique, electrolysis has ceased to be a common treatment for cancer, but it is still frequently used (under the name of electrocautery) to stop the bleeding of small blood vessels. Dermatologists also continue to use it to remove warts, moles, and hair.

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